Search results for "Two-photon absorption"
showing 10 items of 20 documents
Two-Photon Absorption Properties and Structures of BODIPY and Its Dyad, Triad and Tetrad.
2018
A series consisting of a dyad, a triad and a tetrad containing either two, three and four BODIPY units, respectively, has been synthesized and fully characterized and compared to two mono-BODIPY analogs (used as references). The one- and two-photon photophysical properties have been measured and the X-ray structures of four of the BODIPY derivatives have been determined. In the 700-900 nm range, the two-photon absorption (TPA) cross sections range from 30 GM to 160 GM for these compounds.
Two-photon absorption of BF2-carrying compounds: insights from theory and experiment
2017
This communication presents a structure–property study of a few novel pyridine-based difluoroborate compounds with a N–BF2–O core, which exhibit outstanding fluorescence properties. To exploit their potential for two-photon bioimaging, relationships between the two-photon action cross section and systematic structural modifications have been investigated and unravelled.
The influence of sigma and pi acceptors on two-photon absorption and solvatochromism of dipolar and quadrupolar unsaturated organic compounds.
2003
Two-photon absorption cross sections delta and solvatochromic properties were determined for a series of quadrupolar and dipolar compounds by using femtosecond excitation in the spectral range between 710 and 960 nm. The compounds investigated were distyrylbenzenes and polyenes bearing appropriate pi or sigma acceptors. The delta values for the centrosymmetric compounds trans, trans- 1,4-bis[2-(2',5'-dihexyloxy)phenylethenyl]-2,3,5,6-tetrafluorobenzene (6), trans, trans-1,4-bis[2-(4'-dibutylamino)phenylethenyl]- 2,3,5,6-tetrafluorobenzene (2), trans, trans-1,4-bis[2-(4'dimethylamino)phenylbutadienyl]- 2,3,5,6-tetrafluorobenzene (7), trans,-trans-1,4-bis[2-(4'-dimethylamino)phenylethenyl]2,5…
Multifunctional derivatives of dimethoxy-substituted triphenylamine containing different acceptor moieties
2020
This project has received funding from the Research Council of Lithuania (LMTLT), Agreement No. [S-LZ-19-2]. This research was funded by the Région Centre, the Tunisian ministry of research, University of Monastir and the French ministry of Higher Education and Research. J. Bouclé would like to thank the Sigma-Lim LabEx environment for financial supports, and the PLATINOM facility at XLIM laboratory regarding device fabrication and characterizations. DG acknowledges the Lithuanian Academy of Sciences for the financial support.
Two-photon absorption dye based on 2,5-bis(phenylacrylonitrile)thiophene with aggregration enhanced fluorescence
2016
This paper reports the synthesis and characterization of a 2,5-bis(phenylacrylonitrile) thiophene based two-photon dye, designed to show enhancement in fluorescence quantum yield in nanoaggregated form. Strong solvatochromism has been observed and explained by the favoritism of locally excited (LE) or internal charge transfer (ICT) state depending on the solvent polarity. Aqueous dispersions of nanoparticles have been prepared and investigated regarding their optical properties which were correlated to the LE and ICT state and the molecular structure of the aggregates. (C) 2016 Optical Society of America
Continuous-wave spontaneous lasing in mercury pumped by resonant two-photon absorption
2010
The first continuous-wave two-photon absorption laser-induced stimulated emission (CTALISE) is demonstrated. The 7^1S-6^1P transition in mercury at 1014nm wavelength is used and selective lasing of different isotopes is observed.
Nanofabrication on 2D and 3D Topography via Positive‐Tone Direct‐Write Laser Lithography
2019
Direct laser writing (DLW) lithography using two‐photon absorption is a powerful technique mostly used for fabrication of complex structures in micro‐ and nanoscale, by photopolymerizing a negative‐tone resist. In contrast, in this study it is demonstrated that DLW is also well suited for fabricating nano‐ to microscale metallic structures using lift‐off and a positive‐tone photoresist. It is shown first that versatile, fast and large area fabrication is possible on flat two‐dimensional insulating substrates, and an expression for how the line width varies with the scanning speed is derived, with excellent agreement with the experiments. Even more interestingly, a unique application for the…
Determination of third-order nonlinear optical properties of ABI derivatives
2019
This material is based upon work supported by the ERDF 1.1.1.1 activity project Nr. 1.1.1.1/16/A/046 “Application assessment of novel organic materials by prototyping of photonic devices”.
Determination of Kerr and two-photon absorption coefficients of ABI thin films
2018
This material is based upon work supported by the ERDF 1.1.1.1 activity project Nr. 1.1.1.1/16/A/046 “Application assessment of novel organic materials by prototyping of photonic devices”
Enhanced Charge Collection in SiC Power MOSFETs Demonstrated by Pulse-Laser Two-Photon Absorption SEE Experiments
2019
A two-photon absorption technique is used to understand the mechanisms of single-event effects (SEEs) in silicon carbide power metal–oxide–field-effect transistors (MOSFETs) and power junction barrier Schottky diodes. The MOSFETs and diodes have similar structures enabling the identification of effects associated specifically with the parasitic bipolar structure that is present in the MOSFETs, but not the diodes. The collected charge in the diodes varies only with laser depth, whereas it varies with depth and lateral position in the MOSFETs. Optical simulations demonstrate that the variations in collected charge observed are from the semiconductor device structure and not from metal/passiva…